Turkey
Research Article
Preparation and Characterization of Thermoplastic Elastomers/Plasticizer
- Compatibilizer/Organoclay Nanocomposites by Reactive Extrusion
System
Author(s): Mostafa AD, Zakir MOR and Erdoğan AMostafa AD, Zakir MOR and Erdoğan A
Polymer layered silicate nano-composites were prepared in melt by reactive extrusion (25:1 21 mm Rondol twinscrew compounding line) using poly(ethylene-co-propylene- co-ethylidenenorbornene) terpolymer (EPDM) as a matrx polymer, PP-g-MA and poly[(maleic anhydride-alt-1-octadecene)-g-PEO (poly(MA-alt-OD)-g-PEO) as functionalized polymer compatibilizer-internal plasticizer, octadecyl amine-montmorillonite (ODA-MMT) and dimethyldidodecyl ammonium -MMT (DMDA-MMT) as reactive and non-reactive nano-fillers, respectively. The formation of nano structural fragments, polymer blend composition-properties (thermal behavior and morphology) was studied using FTIR, XRD, TGA-DTG and DSC analysis methods. It was found that intercalation/exfoliation degree of EPDM macromolecules significantly depends on the origin and content of organoclays. Better results were obtained for nanocomposites prepared in .. Read More»
DOI:
10.4172/2150-3494.1000166
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