25250, Erzurum
Turkey
Research Article
Compared with a-Fe2O3 and ZnxFe3-XO4 Thin Films Grown by Chemical Spray Pyrolysis
Author(s): Saritaş S, Turgut E, Kundakci M, Gürbulak B and Yildirim MSaritaş S, Turgut E, Kundakci M, Gürbulak B and Yildirim M
This work describes hematite (a-Fe2O3) and ZnxFe3-XO4 thin films prepared by Chemical Spray Pyrolysis (CSP) method. CSP method allows an optimal control of stoichiometry and impurity incorporation, hematite films modified with Zn2+ was also prepared. Moreover, the most attracting characteristics of the hematite are its stability in neutral and basic solutions, abundance and band gap energy (2.0–2.2 eV) which permits it to absorb approximately 40% of the incident solar spectrum on earth. Nevertheless, the performance of hematite electrodes for water oxidation is restricted by their poor charge transport properties. Hematite has low conductivity and low charge-carrier mobility. In addition, the photoexcited electron–hole pairs have short life time (~10-12 s), which makes the hole diffusion length to be also short (2–4 nm). The charge transport properties of hematite ca.. Read More»