Synthesis and structural elucidation of Ni (II), Cu (II), Zn (II) and Cd (II) metal complexes of oxazoline based ligands

International Conference on Smart Materials & Structures

June 15 -17, 2015 Las Vegas, USA

Muluye Melak Zenebe

Posters-Accepted Abstracts: J Material Sci Eng

Abstract :

Synthesis of 2-(2â??-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non-electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.