Theoretical IR, UV, 1H and 13C-NMR spectra of certain Schiff bases derived substituted-2-aminophenol and hydroxyl benzaldehyde

4^th European Chemistry Congress

May 11-13, 2017 Barcelona, Spain

Dila Ercengiz, Halil Berber and Ulku Dilek Uysal

Anadolu University,Turkey

Posters & Accepted Abstracts: Chem Sci J

Abstract :

Schiff bases are compounds formed by the condensation of an active carbonyl group with primary amine or N-substituted imine containing an imino group (R-C=N-). They have been used as ligands, liquid crystals, heterogeneous catalysts, high-performance organic light emitting diodes (OLED), and to design molecular ferromagnet, in catalysis and biological applications [1]. In this study, five Schiff bases (Figure 1) have been synthesized and characterized with 1H and 13C-NMR. These Schiff bases� Gibbs Free Energies, Dipole moments, HOMO-LUMO values, theoretical IR, UV, 1H and 13C-NMR spectra have been researched by DFT method with Gaussian09 program (B3LYP/6-311++G(d,p)) [2] and compared than those with experimental values. Structure- reactivity relationship for these molecules was also searched.

Biography :

Dila Ercengiz has completed her Bachelor’s degree in 2015 from Anadolu University. She is student of Anadolu University at Graduate School of Sciences.
Email:dercengiz@anadolu.edu.tr